The verdict
If you run a blog, a B2B site or a store with steady traffic and the email list is the bottleneck, pick OptinMonster. The targeting rules are the reason to choose it over a simple form, and it is less to set up.
If you run an online store with strong traffic and someone who will own segments, tests and results, pick Justuno. Its targeting is deeper, and Klaviyo is a natural partner for sending the messages.
I'd pick OptinMonster for most readers of this site, because most small B2B teams are not running a store. In both cases, run your own test against your current pop-up. Do not rely on the vendors' opt-in rate claims.