The verdict
For a small B2B or service team, I'd pick ActiveCampaign. Postscript is built for Shopify retention, not lead follow-up, so a B2B team would still need somewhere to run sales.
If you sell on Shopify and want SMS to carry real revenue, I'd pick Postscript. The compliance support and opt-in tools are the reasons to choose it over a feature bolted onto an email tool.
The pricing shapes differ too. ActiveCampaign prices by contacts, so cost rises as your list grows. Postscript bills by message, with carrier fees shown on their own line, so cost follows your sending and a sale week costs more than a quiet one. Forecast both before you commit. A store on another platform should check the fit with Postscript first.